Polyethylene terephthalate filament having high tenacity for industrial use

ABSTRACT

A polyethylene terephthalate monofilament obtained by spinning a polyethylene terephthalate chip having an intrinsic viscosity of 0.8 to 1.3, which gives a stress-strain curve exhibiting an elongation of less than 2.5% at an initial stress of 2.0 g/d, with an initial modulus value of 80 to 160 g/d, an elongation of 7.5% or less in a stress range of from 2.0 g/d to 9.0 g/d, and an elongation of at least 2.0% or more in a stress range of from 10.0 g/d to the point of break, is provided.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a polyethylene terephthalatemonofilament fiber which gives a stress-strain curve exhibiting anelongation of at least 2.0% or more in a stress range of from 10.0 g/dto the point of break. The monofilament fiber according to the inventionis characterized by high tenacity, high modulus and low strain, and thuscan be used for the production of high tenacity polyester fiber forindustrial use, which is used as the material for industrial rope,reinforcement material for construction, webbing or seatbelt.

2. Description of the Related Art

As a useful conventional method for enhancing the tenacity of polyesterfibers for industrial use, there is available a method of melting a highviscosity chip having an intrinsic viscosity of 1.0 or greater, heatingthe melt polymer to a temperature of 310° C. to sufficiently melt thepolymer, solidifying the polymer at a quenching temperature of 15 to 18°C. in a hood of 280 mm long at a hood temperature of 340° C., windingthe polymer at low speed on godet rollers to obtain undrawn yarn,drawing the undrawn yarn directly in a first step and a second step upto a draw ratio of 6.0, and then relaxing the drawn yarn to finally windthe drawn yarn. Here, the characteristic of high tenacity is obtained bydecreasing the degree of orientation of the undrawn yarn through lowspeed winding, and by drawing the undrawn yarn at a high draw ratio. Thepolyester yarn produced by the conventional method as described abovehas a modulus value of 60 g/d to 100 g/d, a stress of 9.5 g/d or less,and an elongation at break of 13 to 18%.

When the draw ratio is increased to obtain a fiber of higher tenacityusing such conventional spinning technology, a processing problem ofyarn break during spinning and fluffing frequently occur, resulting inpoor post-processing properties. Therefore, the conventional technologyleads to an increase in the production costs and lowering of the productquality, and thus it is difficult to obtain high tenacity yarnstherefrom.

SUMMARY OF THE INVENTION

Accordingly, it is an object of the present invention to provide apolyethylene terephthalate monofilament fiber which has a stress-strainprofile exhibiting an elongation of at least 2.0% or more in a stressrange of from 10.0 g/d to the point of break.

The fiber according to the invention is produced by a method ofadjusting the areas of contact between the yarn and the godet rollers,on which initial drawing and secondary drawing are performed, so as toincrease the draw ratio, thus enabling drawing at a draw ratio of 6.5,which is higher than the conventionally achieved draw ratio of 6.0.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic diagram illustrating the production process forthe polyethylene terephthalate filament according to the presentinvention;

FIG. 2 is a graph showing the stress-strain curves for monofilaments ofthe 1500D polyethylene terephthalate filament of the present inventionand a conventional 1500D polyethylene terephthalate filament; and

FIG. 3 is a graph showing the stress-strain curves for monofilaments ofthe 1000D polyethylene terephthalate filament of the present inventionand a conventional 1000D polyethylene terephthalate filament.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

According to a preferred embodiment of the present invention, apolyethylene terephthalate monofilament having an intrinsic viscosity of0.8 to 1.3 gives a stress-strain curve exhibiting an elongation of lessthan 2.5% at an initial stress of 2.0 g/d, with an initial modulus valueof 80 to 160 g/d, an elongation of 7.5% or less in a stress range offrom 2.0 g/d to 9.0 g/d, and an elongation of at least 2.0% or more in astress range of from 10.0 g/d to the point of break.

According to another embodiment of the invention, the polyethyleneterephthalate monofilament has a linear density of 3 to 30 denier.

According to another embodiment of the invention, a multifilamentconsisting of an aggregate of 50 to 40,000 polyethylene terephthalatemonofilaments is provided.

According to another embodiment of the invention, a multifilamentconsisting of an aggregate of 192 or 384 polyethylene terephthalatemonofilaments is provided.

According to another embodiment of the invention, the multifilament hasa stress of 10 to 13 g/d.

According to another embodiment of the invention, the multifilament hasan elongation at break of 9.5 to 13.5%.

The invention provides industrial products such as industrial rope,reinforcement material for construction, webbing or seatbelt, all ofwhich comprise the multifilament.

According to the invention, in the case of a high tenacity polyethyleneterephthalate yarn used for industrial rope, reinforcement material forconstruction, webbing or seatbelt, the stress-strain curve of thepolyethylene terephthalate monofilament is adjusted for the purpose ofminimizing the initial elongation against the impact occurring,initially under an external force. The stress-strain curve of thepolyethylene terephthalate monofilament measured at ambient temperaturepreferably exhibits an elongation of less than 2.5% at an initial stressof 2.0 g/d, with an initial modulus value of 80 to 160 g/d, anelongation of 7.5% or less in a stress range of from 2.0 g/d to 9.0 g/d,and an elongation of at least 2.0% or more in a stress range of from10.0 g/d to the point of break.

In the case of using as industrial rope or reinforcement material forconstruction, the polyethylene terephthalate monofilament should havehigh initial modulus and less drawing under initially applied force, soas to prevent sudden deformation. In order to obtain such material, thepolyethylene terephthalate monofilament of the invention preferably hasan elongation of less than 2.5% at an initial stress of 2.0 g/d, and aninitial modulus value of 80 to 160 g/d. If the monofilament has anelongation of 2.5% or greater at an initial stress of 2.0 g/d, or has alower modulus value, sudden deformation of the monofilament makes itdifficult to obtain a stress-supporting or reinforcing effect.

Furthermore, the polyethylene terephthalate monofilament used for theproduction of such material has preferably an elongation of 7.5% or lessin the stress range of from 2.0 g/d to 9.0 g/d. When the monofilamenthas an elongation of 7.5% or more, the dimensional stability of themonofilament is decreased, resulting in large deformation and themonofilament can be hardly used as industrial reinforcement material orrope.

In addition, for the purpose of minimizing the storage space throughminiaturization of industrial products such as industrial rope,reinforcement material for construction, webbing or seatbelt, it ispreferable for the polyethylene terephthalate monofilament of theinvention to draw with an elongation of at least 2.0% or more in thestress range of from 10.0 g/d to the point of break. This is because,when the monofilament has an elongation of less than 2.0% from 10.0 g/dto the point of break, the ability of the filament for absorbing themaximum tensile load is insufficient, and thus, industrial productsproduced from small amounts of woven yarns would have insufficienttensile strength.

The present invention will be described in detail with reference to theattached drawings.

In FIG. 1, a polyester chip having an intrinsic viscosity in the rangeof 0.80 to 1.30 is melted in an extruder 11, in which the temperaturecondition is set lower. Here, the temperature of the melted polymer isset to 290 to 305° C., and heat is applied to maintain the temperatureof the gear pump 12. At this time, the temperature of the gear pump 12is adjusted to be low, so that the temperature of the polymer passingthrough the gear pump 12 is maintained at 295 to 310° C. Thermaldecomposition due to exotherm or high temperature as a result of thetemperature adjustment should be suppressed as far as possible, so thatthe characteristic properties of the polymer itself are not lost. Thediameter of the nozzle holes of a spinneret 13 is set to 0.5 to 0.8 φ,while the ratio of the length to the diameter (L/D) of a hole of thespinneret 13 is set to 2 to 3, in order to maintain the spinning draftat a constant level, and to impart high stretchability to the polymer onthe godet roller. The length of a hood heater 14 is extended to 320 to500 mm, and the temperature of the hood heater 14 is raised to 350 to400° C., so that an atmosphere allowing the spun yarn to have anon-crystalline and non-oriented structure is rendered inside the hood.To this non-crystalline, non-oriented yarn thus formed, air at atemperature of 15 to 18° C. is supplied through a high-throughput airsupplying inlet 151 and discharged through an air outlet 152 in thecooling zone 15, thereby allowing rapid quenching of thenon-crystalline, non-oriented yarn. Here, the amount of air supplied isset to 80 to 110 mmAq, while the amount of air discharged is set to 90to 120 mmAq. The non-crystalline, non-oriented yarn which has beensolidified is subjected to oiling to an appropriate extent by using anoiling apparatus 16. Thereafter, a guide of a specific form is appliedto the second godet rollers (GR) 172 so as to adjust the area of contactbetween the multifilament yarn and the roller surface of the second GRto about 1,000 to 15,000 mm², so that primary drawing is performedsmoothly at the second GR 172 and the third GR 173. Then, a guide isapplied prior to the third GR 173 in order to maintain the spread of theyarn constant on the third GR 173, so as to adjust the area of contactbetween the multifilament yarn and the roller surface of the third GR173 to about 5,000 to 25,000 mm², so that secondary drawing is performedsmoothly on the third GR 173 and the fourth GR 174. The multifilament isrelaxed between the fourth GR 174 and the fifth GR 175 and then wound upon a winder 18.

FIG. 2 is a graph showing the stress-strain curves for the monofilamentsof the 1500D polyethylene terephthalate filament of the presentinvention and a conventional 1500D polyethylene terephthalate filament.

FIG. 3 is a graph showing the stress-strain curves for the monofilamentsof the 1000D polyethylene terephthalate filament of the presentinvention and a conventional 1500D polyethylene terephthalate filament.

According to the present invention, the stress-strain curve of apolyethylene terephthalate monofilament can be adjusted to minimize theinitial elongation of the industrial high tenacity yarn caused by theimpact initially applied by external force. The polyethyleneterephthalate monofilament of the invention may result in astress-strain curve which exhibits an elongation of less than 2.5% at aninitial stress of 2.0 g/d, with an initial modulus value of 80 to 160g/d, an elongation of 7.5% or less in a stress range of from 2.0 g/d to9.0 g/d, and an elongation of at least 2.0% or more in a stress range offrom 10.0 g/d to the point of break.

According to the invention, the process which is used for obtaining suchstress-strain curve comprises the steps of rendering an atmosphere inthe hood such that a polyethylene terephthalate monofilament can have amaximally non-crystalline and non-oriented structure while passingthrough the hood heater 14, and rapidly quenching the non-crystalline,non-oriented yarn thus formed in the cooling zone 15 to maintain thenon-crystalline and non-oriented state as far as possible, so as toallow operation with a high draw ratio.

The factor which highly affects the stress-strain curve for themonofilament of the invention is the areas of contact between the yarnand the godet rollers, on which the initial primary drawing andsecondary drawing occur. As the contact areas are adjusted, a preferablestress-strain curve for the monofilament of the invention is obtained.The polyethylene terephthalate filament which has passed through thecooling zone 15 has constant contact areas with the surfaces of thesecond GR 172 and the third GR 173, which highly affect the initialprimary drawing and the secondary drawing. The area of contact betweenthe multifilament yarns with the surface of the godet rollers used forthe initial primary drawing is preferably 4,000 to 8,000 mm^(2,) whilethe area of contact between the multifilament yarns with the surface ofthe godet rollers used for the secondary drawing is preferably 14,000 to18,000 mm^(2.) When the area of contact between the multifilament yarnsand the surface of the godet rollers used for the initial primarydrawing is less than 4,000 mm², or when the area of contact between themultifilament yarn and the surface of the godet rollers used for thesecondary drawing is less than 14,000 mm^(2,) uniform heat transfer isnot achieved between the multifilaments. Furthermore, non-uniformity ofthe flowing agent causes reduction in the stretchability, and it isdifficult to obtain a preferable stress-strain curve for themonofilament of the invention. On the contrary, when the area of contactbetween the multifilament yarn and the surface of the godet rollers usedfor the initial primary drawing is larger than 8,000 mm^(2,) or when thearea of contact between the multifilament yarn and the surface of thegodet rollers used for the secondary drawing is larger than 18,000mm^(2,) there are problems such as generation of fluff due to contactbetween filaments, and tar generation. Therefore, the contact areasshould be suitably adjusted in order for the non-crystalline,non-oriented monofilament to obtain the maximum stretchability.

There are many factors affecting the area of contact betweenmultifilament yarn and godet roller surface. The area of contactincreases proportionally to the number of winding (number of turn) ofthe filament wound on the godet rollers for drawing. That is, the numberof winding can be adjusted to adjust the area of contact. Anotherimportant factor is that a guide having a certain form is applied tomaintain the spread of the yarn between the godet rollers constant, sothat the yarn width of the yarn wound on the godet rollers can beadjusted. For example, if the guide takes a form of a narrow V-shapedgroove, the yarn width is reduced, and eventually the contact area isreduced. If the guide takes a flat form, the yarn width is increased,and the contact area is increased. Another factor for adjusting thecontact area is the drawing tension of the roller, drawing temperature,amount of flowing agent, and the like.

A preferable stress-strain curve of the monofilament of the inventioncan be obtained by adjusting the area of contact of the multifilamentyarn with the surface of the second GR 172, which largely affects theprimary drawing, to 4,000 to 8,000 mm^(2,) while adjusting the area ofcontact of the multifilament yarn with the surface of the third GR 173,which are the godet rollers used for the secondary drawing, to 14,000 to18,000 mm^(2,) by organically combining various factors.

The polyethylene terephthalate multifilament obtained by aggregating 50to 40,000 polyethylene terephthalate monofilaments produced through suchprocess, has good spinnability and thus is advantageous in the aspectsof external appearance and fluffing. Also, the polyethyleneterephthalate multifilament has a stress of 10 to 13 g/d, a modulus of110 to 140 g/d, and an elongation at break of 9.5 to 13.5% or less, andthus can be widely used as an industrial polyester fiber which is usefulfor industrial rope, reinforcement material for construction, webbingand seatbelt.

The property evaluations in the following Examples and ComparativeExamples were performed as follows.

1) Intrinsic Viscosity (I.V.)

0.1 g of a sample is dissolved in a reagent comprising a mixture ofphenol and 1,1,2,2-tetrachloroethaanol at a weight ratio of 6:4 at 90°C. for 90 minutes, and then the solution is transferred to an Ubbelohdeviscometer, which is then maintained in a constant temperature bath at30° C. for 10 minutes. The time in seconds taken by the solution indropping is measured by using a viscometer and an aspirator. The time inseconds taken by the solvent in dropping is also measured by the samemethod as described above, and the R.V. value and the I.V. value arecalculated according to the following equations:R.V.=Time in seconds taken by the sample in dropping/Time in secondstaken by the solvent in droppingI.V.=¼×[(R.V.−1)/C]+¾×(In R.V./C)

In the above equation, C represents the concentration (g/100 ml) of thesample in the solution.

2) Measurement of Modulus, Strength and Elongation of Multifilament

The original yarn is left to stand under standard conditions, that is,in a constant temperature and constant humidity chamber at a temperatureof 25° C. and at a relative humidity of 65% for 24 hours, and then asample is subjected to the measurement according to the method of ASTM2256 using a tensile test machine. The properties of the multifilamentare measured by using an average of 8 values, excepting one minimumvalue and one maximum value, from 10 values obtained from measurement of10 multifilaments. The initial modulus indicates the gradient of thestress-strain curve before the yield point.

3) Tenacity (g/d), Elongation at Specific Load (%) and Modulus (g/d) ofMonofilament

Ten monofilaments are extracted from an original yarn (multifilament)which has been left to stand at a temperature of 25° C. and at arelative humidity of 65 RH % for 24 hours. Subsequently, a load (weak,monodenier×60 (mg)) defined according to the denier number was appliedto a sample having a length of 20 mm by using a monofilament tensiletest machine Vibrojet 2000 manufactured by Lenzing Gruppe, and then theinitial load was measured at a tensile rate of 20 mm/min. The propertiesof the monofilament are measured by using an average of 8 values,excepting one minimum value and one maximum value, from 10 measuredvalues. The initial modulus indicates the gradient of the stress-straincurve before the yield point.

4) External Appearance

The original yarn which is wound on a winder in a cake form is observedwith naked eyes for 5 minutes using a Stroboscope, for the presence orabsence of fluff.

5) Number of Fluff

The original yarn is measured along a length of 30,000 m by using aPilot Warper testing machine at a yarn speed of 300 to 500 m/min and ata sensitivity of 2.5 to 4.5 levels (relative value).

6) Proccessability

The frequency of yarn break occurring only on the godet rollers isdetermined by observing the original yarn at a single position for 24hours.

7) Area of Contact between Yarn and Godet Roller Surface

The yarn width at the first turning point is determined by photographicmeasurement, and the yarn width at the final turning point is determinedin the same manner, thus to obtain an average of the two values. Thecontact area is calculated by the equation:Contact area=average yarn width×number of turns×radius of godet roller×2(for a pair of godet rollers)

EXAMPLES Examples 1 to 3

A polyester chip having an intrinsic viscosity of 1.00 was melted, andthe melt polymer was extruded through a nozzle having 192 orifices, eachorifice having a diameter of 0.6 mm and a ratio of length and diameter(L/D) of 3. The extruded polymer was quenched with air at 15° C.,gathered and oiled. Subsequently, the filament was subjected to winding5 turns at the second godet rollers (primary drawing point) at 100° C.,and 7 turns at the third godet rollers (secondary drawing point) at 125°C., with the ratio of the primary draw at the second godet rollers andthe third godet rollers to the secondary draw at the third godet rollersand the fourth godet rollers being 75%:25%. A guide in a flat formhaving a 4 mm-wide groove was applied before the second godet rollersand the third godet rollers. The speed of the fourth godet rollers wasset at 2700 m/min. Thus, filaments of 1500 denier each were spun anddrawn under the spinning conditions presented in Table 1. The resultsare given in Table 5.

Comparative Example 1

A filament was produced in the same manner as in Examples 1 to 3described above, except that a guide in a flat form having a 6.5 mm-widegroove was applied before the second and third godet rollers, and thefilament was subjected to winding 5 turns at the second godet rollersand 7 turns at the third godet rollers.

Comparative Example 2

A filament was produced in the same manner as in Comparative Example 1,except that a guide in a flat form having a narrow V-shaped groove(width of the guide groove being 2.5 mm) was applied before the secondand third godet rollers, and the filament was subjected to winding 6turns 5 at the second godet rollers and 8 turns at the third godetrollers. TABLE 1 Example Example Example Comp. Comp. Condition 1 2 3 Ex.1 Ex. 2 Temperature 295 297 300 285 310 of melt polymer (° C.)Temperature 300 305 310 285 315 of polymer in gear pump (° C.) Length of320 380 440 250 550 hood heater (mm) Temperature 350 375 400 320 410 ofhood heater (° C.) Pressure of 90/100 110/120 110/120 50/60 130/140quenching air (mmAq) Area of 6500 6000 5500 11000 3500 contact with2^(nd) GR (mm²) Area of 15500 14500 13500 20000 12000 contact with3^(rd) GR (mm²) Total 6.4 6.5 6.55 6.0 6.3 draw ratio Denier 1510 15081518 1509 1516

Examples 4 to 6

A polyester chip having an intrinsic viscosity of 1.05 was melted, andthe melt polymer was extruded through a nozzle having 192 orifices, eachorifice having a diameter of 0.6 mm and a ratio of length and diameter(L/D) of 3. The extruded polymer was quenched with air at 15° C.,gathered and oiled. Subsequently, the filament was subjected to winding6 turns at the second godet rollers (primary drawing point) at 100° C.,and 7 turns at the third godet rollers (secondary drawing point) at 125°C., with the ratio of the primary draw at the second godet rollers andthe third godet rollers to the secondary draw at the third godet rollersand the fourth godet rollers being 73%:27%. A guide in a flat formhaving a 4 mm-wide groove was applied before the second godet rollersand the third godet rollers. The speed of the fourth godet rollers wasset at 2700 m/min. Thus, filaments of 1500 denier each were spun anddrawn under the spinning conditions presented in Table 2. The resultsare given in Table 5.

Comparative Example 3

A filament was produced in the same manner as in Examples 4 to 6described above, except that a guide in a flat form having a 6.5 mm-widegroove was applied before the second and third godet rollers, and thefilament was subjected to winding 5 turns at the second godet rollersand 7 turns at the third godet rollers.

Comparative Example 4

A filament was produced in the same manner as in Comparative Example 3,except that a guide having a narrow V-shaped groove (width of the guidegroove being 2.5 mm) was applied before the second and third godetrollers, and the filament was subjected to winding 6 turns at the secondgodet rollers and 8 turns at the third godet rollers. TABLE 2 ExampleExample Example Comp. Comp. Condition 4 5 6 Ex. 3 Ex. 4 Temperature 298300 302 299 320 of melt polymer (° C.) Temperature 305 308 310 300 315of polymer in gear pump (° C.) Length of 320 380 440 250 550 hood heater(mm) Temperature 350 375 400 320 440 of hood heater (° C.) Pressure of90/100 110/120 110/120 40/50 130/140 quenching air (mmAq) Area of 70006500 6000 11500 3800 contact with 2^(nd) GR (mm²) Area of 16000 1500014000 21000 12500 contact with 3^(rd) GR (mm²) Total 6.3 6.4 6.5 5.9 6.2draw ratio Denier 1520 1514 1525 1511 1517

Examples 7 to 9

A polyester chip having an intrinsic viscosity of 1.00 was melted, andthe melt polymer was extruded through a nozzle having 192 orifices, eachorifice having a diameter of 0.6 mm and a ratio of length and diameter(L/D) of 3. The extruded polymer was quenched with air at 15° C.,gathered and oiled. Subsequently, the filament was subjected to winding5 turns at the second godet rollers (primary drawing point) at 100° C.,and 8 turns at a third godet rollers (secondary drawing point) at 125°C., with the ratio of the primary draw at the second godet rollers andthe third godet rollers to the secondary draw at the third godet rollersand the fourth godet rollers being 75%:25%. A guide in a flat formhaving a 4 mm-wide groove was applied before the second godet rollersand the third godet rollers. The speed of the fourth godet rollers wasset at 3000 m/min. Thus, filaments of 1000 denier each were spun anddrawn under the spinning conditions presented in Table 3. The resultsare given in Table 5.

Comparative Example 5

A filament was produced in the same manner as in Examples 7 to 9described above, except that a guide in a flat form having a 6.5 mm-widegroove was applied before the second and third godet rollers, and thefilament was subjected to winding 5 turns at the second godet rollersand 8 turns at the third godet rollers.

Comparative Example 6

A filament was produced in the same manner as in Comparative Example 5,except that a guide having a narrow V-shaped groove (width of the guidegroove being 2.5 mm) was applied before the second and third godetrollers, and the filament was subjected to winding 7 turns at the secondgodet rollers and 9 turns at the third godet rollers. TABLE 3 ExampleExample Example Comp. Comp. Condition 7 8 9 Ex. 5 Ex. 6 Temperature 295297 300 285 310 of melt polymer (° C.) Temperature 300 305 310 285 315of polymer in gear pump (° C.) Length of 320 380 400 250 550 hood heater(mm) Temperature 350 375 400 320 440 of hood heater (° C.) Pressure of90/100 110/120 110/120 40/50 130/140 quenching air (mmAq) Area of 67006200 5700 11000 3200 contact with 2^(nd) GR (mm²) Area of 15500 1450013500 20500 12000 contact with 3^(rd) GR (mm²) Total 6.40 6.44 6.48 6.006.30 draw ratio Denier 1010 1004 1018 1013 1016

Examples 10 to 12

A polyester chip having an intrinsic viscosity of 1.05 was melted, andthe melt polymer was extruded through a nozzle having 192 orifices, eachorifice having a diameter of 0.6 mm and a ratio of length and diameter(L/D) of 3. The extruded polymer was quenched with air at 15° C.,gathered and oiled. Subsequently, the filament was subjected to winding5 turns at the second godet rollers (primary drawing point) at 100° C.,and 8 turns at the third godet rollers (secondary drawing point) at 125°C., with the ratio of the primary draw at the second godet rollers andthe third godet rollers to the secondary draw at the third godet rollersand the fourth godet rollers being 70%:30%. A guide in a flat formhaving a 4 mm-wide groove was applied before the second godet rollersand the third godet rollers. The speed of the fourth godet rollers wasset at 3000 m/min. Thus, filaments of 1000 denier each were spun anddrawn under the spinning conditions presented in Table 4. The resultsare given in Table 5.

Comparative Example 7

A filament was produced in the same manner as in Examples 10 to 11described above, except that a guide in a wide flat form having a 6.5mm-wide groove was applied before the second and third godet rollers,and the filament was subjected to winding 5 turns at the second godetrollers and 8 turns at the third godet rollers.

Comparative Example 8

A filament was produced in the same manner as in Comparative Example 7,except that a guide having a narrow V-shaped groove (width of the guidegroove being 2.5 mm) was applied before the second and third godetrollers, and the filament was subjected to winding 4 turns at the secondgodet rollers and 9 turns at the third godet rollers. TABLE 4 ExampleExample Exam- Comp. Comp. Condition 10 11 ple 12 Ex. 7 Ex. 8 Temperature296 297 298 299 320 of melt polymer (° C.) Temperature 310 310 310 300315 of polymer in gear pump (° C.) Length of 320 380 400 250 550 hoodheater (mm) Temperature 350 375 400 320 440 of hood heater (° C.)Pressure of 90/100 110/120 110/120 40/50 130/140 quenching air (mmAq)Area of 7000 6500 5900 11500 3600 contact with 2^(nd) GR (mm²) Area of16000 15000 14000 21000 12500 contact with 3^(rd) GR (mm²) Total 6.306.35 6.4 5.85 6.15 draw ratio Denier 1010 1004 1018 1013 1016

TABLE 5 Drawn Yarn Monofilament Processability Elongation ElongationAppearance Number of (yarn under under (presence fluffs breaking stressof stress of or absence (entities/ entities/ Elongation Elongation 2.0g/d to 10.0 g/d to of fluff or 30,000 Day × Tenacity at break at 2.0 g/d9.0 g/d break point loop) meter) position) (g/d) (%) (%) (%) (%) Ex. 1 00 0.5 11.16 12.8 2.0 6.7 2.6 Ex. 2 0 0 1.2 11.55 12.1 1.9 6.5 2.7 Ex. 30 0 1.3 11.90 11.7 1.9 6.0 3.1 Ex. 4 0 0 0.9 11.33 12.3 1.7 6.6 2.4 Ex.5 0 1 1.5 11.68 11.6 1.8 6.1 2.8 Ex. 6 0 1 1.6 12.08 11.1 1.7 5.8 2.9Ex. 7 0 0 0.5 11.78 13.2 2.1 5.9 4.0 Ex. 8 0 0 0.8 11.90 12.6 1.8 5.74.4 Ex. 9 0 0 0.9 12.33 11.9 1.7 5.7 4.4 Ex. 10 0 0 0.9 11.69 13.1 2.05.9 4.3 Ex. 11 0 0 1.3 11.98 12.3 1.8 5.6 4.7 Ex. 12 0 1 1.5 12.45 11.91.7 5.6 4.4 Comp. 6 20 or more 3.5 10.17 17.0 2.8 10.3 0.5 Ex. 1 Comp. 47 2.8 10.90 15.2 2.6 7.9 1.1 Ex. 2 Comp. 20 or more 20 or more 3.2 10.2216.4 2.5 8.8 0.5 Ex. 3 Comp. 9 11 2.7 10.89 15.6 2.4 7.9 1.0 Ex. 4 Comp.3 9 3.7 9.82 17.1 2.7 10.8 0 Ex. 5 Comp. 2 5 3.2 10.33 15.8 2.4 8.2 0.9Ex. 6 Comp. 5 20 or more 4.3 9.98 17.0 2.5 10.4 0 Ex. 7 Comp. 2 6 3.110.43 15.9 2.3 7.8 1.2 Ex. 8

The present invention is effective in maintaining the intrinsicproperties of polyethylene terephthalate chip as much as possible, andin allowing excellent spinnability by optimizing the spinningconditions, thus suppressing generation of fluffs. The invention canprovide an industrial high tenacity polyethylene terephthalate yarnhaving high modulus, high tenacity and low elongation at break due tohigh ratio drawing, which is useful for industrial rope, reinforcementmaterial for construction, webbing, seatbelt and the like.

1. A polyethylene terephthalate monofilament, which is obtained byspinning a polyethylene terephthalate chip having an intrinsic viscosityof 0.8 to 1.3, wherein the polyethylene terephthalate monofilament givesa stress-strain curve exhibiting an elongation of less than 2.5% at aninitial stress of 2.0 g/d, with an initial modulus value of 80 to 160g/d, an elongation of 7.5% or less in a stress range of from 2.0 g/d to9.0 g/d, and an elongation of at least 2.0% or more in a stress range offrom 10.0 g/d to the point of break.
 2. The polyethylene terephthalatemonofilament according to claim 1, wherein the linear density of thepolyethylene terephthalate is 3 to 30 denier.
 3. A polyethyleneterephthalate multifilament, which is obtained by aggregating 50 to40,000 polyethylene terephthalate monofilaments according to claim
 1. 4.The polyethylene terephthalate multifilament according to claim 3, whichis obtained by aggregating 192 or 384 polyethylene terephthalatemonofilaments.
 5. The polyethylene terephthalate multifilament accordingto claim 3, wherein the strength of the polyethylene terephthalatemultifilament has a stress of 10 to 13 g/d.
 6. The polyethyleneterephthalate multifilament according to claim 3, wherein the elongationat break of the polyethylene terephthalate multifilament is 9.5 to13.5%.
 7. An industrial product selected from the group consisting ofindustrial rope, reinforcement material for construction, webbing andseatbelt, all of which comprise the polyethylene terephthalatemultifilament according to claim 3.